The Best way to Learn is to buy a Book and and practice what is in the book. I bealive i donated a book to you some time ago, how is going ?
If you are from vb6, just jump straight to .NET you can choose to build web or windows application, you might learn to specialize but don't limit your self.
It is true that there are more C# examples online than vb.net example. It is not because VB.NET is weak or its about to die, but this is a preference that people have over other languages.
I wrote Vb.net articles before in in CodeProject" and never wrote any vb.net article in .Netfunda, i cant explain that i just grew and love the other language, not because the other one is better than the other , just because i am comfortable with it.
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