Declare @temp table(Name varchar(50))
insert into @temp values
('Raja Rao'),('Arul Pandi'),('Mahesh Babu'),('Suresh Kumar')
Select Name [Name with Space]
,Substring(Name,0,charindex(' ',Name))+
LTRIM(Substring(Name,charindex(' ',Name)+1,LEN(Name)-charindex(' ',Name))) [Name without Space]
from @temp