By approaching below code,we can avoid null values
Make shared function as below:
Public Shared Function Check_Session_Value_Null(ByVal session_value As HttpSessionState,ByVal key_item As String) As String
Dim result As String = string.empty
if session_value(key_item) <> Nothing Then
result = session_value(key_item)
End If
Return result
End Function
And call above function in any method.