"The network path was not found" FileStream Issue

Ok I have a problem that is aggravating and I can not seem to get it worked out.  I am creating a FileStream for a file in code.  Once this is deployed to the server I receive the following exception:
Message: The network path was not found.
Source: mscorlib
Stack Trace: at System.IO.__Error.WinIOError(Int32 errorCode, String maybeFullPath)
   at System.IO.FileStream.Init(String path, FileMode mode, FileAccess access, Int32 rights, Boolean useRights, FileShare share, Int32 bufferSize, FileOptions options, SECURITY_ATTRIBUTES secAttrs, String msgPath, Boolean bFromProxy)
   at System.IO.FileStream..ctor(String path, FileMode mode, FileAccess access, FileShare share, Int32 bufferSize, FileOptions options)
   at MyAppTest
Ok before you jump on this thread, all of the following are occurring (read all please):
In code, a super duper domain Admin account ...